新疆含煤盆地煤中主要富集金属元素研究进展

Research status and prospect of metals in coals of Xinjiang

  • 摘要:
    背景 新疆为我国西北地区重要的煤炭生产基地,其煤炭资源预测储量占全国的40%,主要分布于准噶尔、伊犁、吐哈和三塘湖等聚煤盆地。
    方法 以战略金属(锂、稀土、锆、铪、铌、钽等)、有害金属(砷、汞、钠等)、放射性金属(铀、钍)以及其他重金属(铁、锰等)为出发点,选取新疆典型煤田进行讨论,旨在探讨煤中金属元素的富集机制和成矿潜力。
    进展 (1) 新疆赋煤区不同聚煤盆地煤中金属元素的富集受多因素协同控制:下二叠统煤中稀有金属的异常富集与古特提斯洋闭合相关火山活动及岩浆热液密切相关;准噶尔盆地侏罗系煤中锂主要赋存于硅铝酸盐矿物(高岭石、伊利石等)中,而钠(Na)则与深部高矿化度地下水的长期作用有关;伊犁盆地侏罗系煤中铀的富集受控于后期氧化还原环境的改变,此外,砷、汞和铊的协同富集可能与硫化物矿物相关;三塘湖盆地锂异常富集与热液流体活动相关。(2) 同一金属元素在不同煤田/盆地的富集程度和富集机制亦存在较大差异。三塘湖盆地锂元素的富集(高至923 μg/g)明显区别于与中国煤中锂含量相近的准噶尔(0.2~19 μg/g)、伊犁(2.56~27.2 μg/g)和哈密(29.6 μg/g)盆地;伊犁盆地砷、铀元素的富集(分别高达234、7 270 μg/g)高于准噶尔盆地(<5、82 μg/g)。
    展望 整体上新疆煤中金属元素的富集,尤其是战略金属元素,具有一定的成矿潜力。但商业化开发仍面临多重挑战:二叠系−侏罗系煤中多金属组合时空分布不明、勘探程度低等。针对上述问题,需通过融合地球物理、地球化学等学科,明确新疆地区重要聚煤盆地沉积煤层中金属元素的富集程度和富集机制,推动煤中战略金属元素的协同开发,形成煤炭资源综合利用的“新疆模式”。

     

    Abstract:
    Background As a crucial coal production base in Northwest China, Xinjiang holds 40% of the nation’s predicted coal reserves, primarily distributed in coal-bearing basins such as Junggar, Yili, Tuha, and Santanghu.
    Method This paper initiates its analysis by focusing on strategic metals (including Lithium, Rare Earth Element, Zirconium, Hafnium, Niobium, and Tantalum), toxic metals (Arsenic, Mercury, and Sodium), radioactive metals (Uranium and Thorium), and other heavy metals (Iron and Manganese). The objective is to comprehensively explore the enrichment mechanisms and metallogenic potential of metal elements in coal within each coalfield of the typical coal-accumulating basins in Xinjiang.
    Progress  Research findings demonstrate that (1) the enrichment of metal elements in coal from Xinjiang is jointly regulated by multiple factors. Specifically, the abnormal enrichment of rare metals in the Lower Permian coal is intricately linked to volcanic activities and magmatic hydrothermal processes associated with the closure of the Paleo-Tethys Ocean. Regarding the Jurassic coal in the Junggar Basin, lithium is predominantly hosted in aluminosilicate minerals (such as kaolinite and illite). Moreover, the presence of sodium can be attributed to the long-term influence of deep, highly mineralized groundwater. In the Jurassic coal of the Yili Basin, the enrichment of uranium is governed by the variation in the subsequent redox environment. Additionally, the concurrent enrichment of arsenic, mercury, and thallium might be associated with sulfide minerals. In the Santanghu Basin, the abnormal enrichment of lithium is correlated with hydrothermal fluid activities. (2) the degree and mechanism of enrichment of the same metal element in different coal fields/basins also vary significantly. The lithium element enrichment in the Santanghu Basin(up to 923 μg/g) is significantly different from the Junggar (0.2~19 μg/g), Yili (2.56~27.2 μg/g) and Hami (29.6 μg/g) basins, which have similar lithium content in their coal; the arsenic and uranium elements in the Yili Basin (up to 234 μg/g and 7270 μg/g, respectively) are higher than those in the Junggar Basin (<5 μg/g and 82 μg/g, respectively).
    Prospect  Overall, the enrichment of metal elements in Xinjiang coal, especially strategic metal elements, has certain potential for mineralization. However, commercial development still faces multiple challenges: the spatial and temporal distribution of multi-metal combinations in the Permian-Jurassic coal is unclear, and the exploration level is low, etc. To address the aforementioned issues, it is necessary to integrate disciplines such as geophysics, geochemistry, and AI transparent geology to clearly determine the enrichment degree and mechanism of metal elements in the sedimentary coal seams of important coal-forming basins in Xinjiang region. This will promote the collaborative development of strategic metal elements in coal and form the "Xinjiang model" for comprehensive utilization of coal resources.

     

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