超深层海相页岩型氦源岩特征与生氦潜力

Characteristics and helium generation potential of ultra-deep marine shales as helium source rocks

  • 摘要:
    目的 规模有效的氦源岩是富氦气田的物质基础。四川盆地威远地区灯影组富氦气藏存在前震旦系基底花岗岩和寒武系筇竹寺组页岩等氦源岩;相较于基底花岗岩,筇竹寺组页岩型氦源岩的富U、Th矿物赋存特征及生氦潜力研究仍旧薄弱。
    方法 以四川盆地威远地区筇竹寺组页岩为研究对象,综合场发射扫描电镜观察、能谱及微量元素分析对筇竹寺组页岩型氦源岩特征和生氦潜力进行研究。
    结果和结论 (1) 研究区筇竹寺组页岩U元素显著富集,而Th元素丰度较低。(2) U、Th赋存主要受控于氧化还原环境。筇竹寺组页岩沉积环境为强还原环境,在此条件下,U以还原沉淀、吸附和络合的形式赋存于有机质、黏土矿物(蒙脱石、绿泥石)、含磷矿物及含铁矿物(菱铁矿)中;Th主要以类质同象的形式赋存于独居石和锆石等稳定矿物中。(3) 筇竹寺组页岩的生氦强度平均为2.41×10−21 m3/(kg·a),高于前震旦系基底花岗岩1.82×10−21 m3/(kg·a)。筇竹寺组页岩生烃强度大,为(20~200)×108 m3/km2,巨量烃类气强烈地“稀释”氦气,导致页岩气藏中氦丰度较低(体积分数为0.018%),削弱了对灯影组天然气藏的供氦效率。相比之下,规模巨大的基底花岗岩通过“溶解−脱溶、断层输导”对灯影组气藏有效供氦,形成了以花岗岩为主、页岩为辅的“双源”供氦模式。

     

    Abstract:
    Objective Large-scale, effective helium source rocks serve as a material basis for the formation of a helium-rich gas field. In the Weiyuan area, Sichuan Basin, the helium-rich gas reservoirs within the Dengying Formation exhibit helium source rocks consisting of the pre-Sinian basement granites and the shales of the Cambrian Qiongzhusi Formation. Compared to the basement granites, studies on the shales of the Qiongzhusi Formation remain limited, including those on the occurrence characteristics of uranium (U)- and thorium (Th)-rich minerals and helium generation potential.
    Methods This study investigated the shales of the Qiongzhusi Formation, Weiyuan area, Sichuan Basin. By integrating field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), and trace element analysis, this study examined the characteristics and helium generation potential of shales as helium source rocks in the Qiongzhusi Formation.
    Results and Conclusions The shales of the Qiongzhusi Formation in the study area exhibit significant U enrichment but a low Th abundance. The occurrence forms of U and Th are primarily governed by redox conditions. The shales of the Qiongzhusi Formation were deposited in a highly reducing environment. Under such a sedimentary setting, U primarily occurs within organic matter, clay minerals (e.g., montmorillonite and chlorite), phosphorus-bearing minerals, and iron-bearing minerals (siderite) through the processes of reduction-precipitation, adsorption, and complexation. In contrast, Th predominantly occurs within stable minerals such as monazites and zircons via isomorphous substitution. The shales of the Qiongzhusi Formation show an average helium generation intensity of 2.41×10−21 m3/(kg·a), higher than that of the pre-Sinian basement granites (1.82×10−21 m3/(kg·a)). However, the shales exhibit a high hydrocarbon generation intensity of approximately (2~200) ×108 m3/km2. As a result, the enormous volumes of hydrocarbon gases significantly dilute helium, leading to low helium abundance (volumetric fraction: 0.018%) within the shale gas reservoirs and weakening the helium supply efficiency of the shales to the gas reservoirs within the Dengying Formation. In contrast, the extensive-scale basement granites effectively supply helium to the gas reservoirs through dissolution-exsolution and transport along faults. Consequently, a dual-source helium supply pattern consisting of granites predominantly and shales secondarily is formed.

     

/

返回文章
返回