N2/CO2驱替煤层CH4非线性渗流特性实验研究

An experimental study on nonlinear seepage characteristics in coal seams during CH4 displacement through N2 and CO2 flooding

  • 摘要:
    背景 我国煤层普遍具有低孔(<5%)、低渗(0.001×10−3 μm2)特性,瓦斯抽采率低。注气驱替强化瓦斯抽采技术在地面煤层气排采、井下瓦斯预抽以及深部CO2地质封存等方面均发挥重要作用。
    方法 选取常见主要驱替及被驱气体N2、CO2、CH4、He为研究对象,结合各气体的物理性质,通过准静态法、气体流量法、雷诺数等计算,分别讨论了各种气体在100、200、300 mm不同煤样特征长度煤心中的渗流行为及特征,分析了启动压力梯度、黏滞阻力以及吸附力对He、N2、CO2、CH4气体渗流特性的影响。
    结果和结论 4种气体在煤心中运移所受阻力规律为FHe>F_\mathrmCO_2 >F_\mathrmCH_4 >F_\mathrmN_2 ;阻力大小与气体分子平均有效直径、动力黏度以及相态变化有关;超临界态气体的密度和黏滞阻力增加,导致其运移阻力显著提高。4种气体的启动压力梯度(λHe>\lambda _\mathrmCO_2 >\lambda _\mathrmCH_4 ≈\lambda _\mathrmN_2 )与煤心长度呈反比关系;启动压力梯度受气体的动力黏度、煤心孔隙特征及吸附性等因素影响。黏滞阻力由气体与孔隙壁面、吸附层之间的相互作用产生;雷诺数(Re _\mathrmCO_2 >Re _\mathrmN_2 >Re _\mathrmCH_2 >ReHe)随注入压力和孔径的增加而增大。煤基质对气体的吸附性显著影响渗透率和渗流速度;N2因其吸附性较弱,孔隙变化小,故渗透率处于较高水平(kHe>k _\mathrmN_2 >k _\mathrmCO_2 >k _\mathrmCH_4 );而CO2由于吸附性较强,会造成煤基质膨胀,导致煤心渗透率偏低;气体在煤心中的运移过程存在临界压力。当注入压力低于临界压力时,气体渗流受吸附作用和滑脱效应影响,表现出非线性特征;当注入压力超过临界压力后,渗流特性趋于稳定,逐渐接近线性流动。该研究结果为驱替工艺参数优化、驱替效率提升及工程现场应用提供理论依据。

     

    Abstract:
    Background Coal seams in China are generally characterized by low porosity (<5%) and low permeability (0.001×10−3μm2), leading to low coalbed methane (CBM, dominated by CH4) drainage efficiency. Gas flooding-enhanced CBM drainage technology plays a significant role in surface CBM drainage, underground CBM pre-drainage, and deep geologic CO2 storage.
    Methods  This study investigated four common types of gases: N2 and CO2 for flooding, CH4 to be displaced, and He for blank control. Based on the physical properties of these gases and employing methods including the quasi-static method, the gas flow rate method, and the Reynolds number, this study explored the seepage behavior and characteristics of the four types of gases in coal cores measuring 100 mm, 200 mm, and 300 mm in length. Furthermore, it analyzed the impacts of the threshold pressure gradient, viscous resistance, and adsorption force on the seepage characteristics of He, N2, CO2, and CH4.
    Results and Conclusions The results indicate that the resistance to the migration of the four types of gases in coal cores decreased in the order of FHe, F_\mathrmCO_2 , F_\mathrmCH_4 , and F_\mathrmN_2 . The magnitude of the resistance was associated with the average effective diameter of gas molecules, the dynamic viscosity of gas, and gas phase change. The increases in the density and viscous resistance of supercritical gas led to significantly elevated resistance to gas migration. The threshold pressure gradients of the four types of gases decreased in the order of λHe, \lambda _\mathrmCO_2 , and \lambda _\mathrmCH_4 (approximately equal to \lambda _\mathrmN_2 ), and they were inversely proportional to the coal core length. The threshold pressure gradients were affected by the dynamic viscosity of gases, the pore characteristics of coal cores, and adsorptivity. The viscous resistance was generated by the interactions between the gases and pore walls and adsorption layers. The Reynolds numbers for the four types of gases decreased in the order of Re _\mathrmCO_2 , Re _\mathrmN_2 , Re _\mathrmCH_4 , and ReHe, increasing with the injection pressure and pore size. The adsorption of coal matrix for gas significantly affected the permeability and seepage velocity. N2 exhibited a high permeability due to the weak adsorption of coals for it and small pore changes, with gas permeability in coal cores decreasing in the order of kHe, k _\mathrmN_2 , k _\mathrmCO_2 , and k _\mathrmCH_4 . Due to the strong adsorption of CO2, it will cause the expansion of coal matrix, resulting in low permeability of coal core. There existed a critical pressure for gas migration in coal cores. When the injection pressure was less than the critical pressure, gas seepage exhibited nonlinear characteristics under the influence of adsorption and slippage effects. Otherwise, the gas seepage tended to be stable and gradually approached linear flow. The results of this study provide a theoretical basis for the process parameter optimization, efficiency enhancement, and engineering applications of CH4 displacement through gas flooding.

     

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