强各向异性抑制镜质体反射率的光学原理以接触变质煤为例

Optical mechanisms behind vitrinite reflectance suppression caused by strong anisotropy: A case study of contact metamorphic coals

  • 摘要:
    目的 镜质体各向异性较弱时呈一轴晶负光性特征,最大反射率(Rmax)代替随机反射率(Rran)可校正各向异性带来的抑制。然而,随着各向异性的增强,镜质体光性特征愈发复杂,Rmax无法反映其热变质温度。
    方法 选取安徽淮北石台井田岩浆侵入煤焦中强各向异性镜质体为研究对象,通过反射正交偏光显微镜(R-PLM)、超高清扫描电镜(SEM)、Rmax和最小反射率(Rmin)的测试,解析镜质体的显微结构、深微织构及光性特征,探究其反射率抑制的显微光学机理。
    结果 (1) 岩浆接触变质形成的强各向异性镜质体内流纹结构炭(flow-texture carbon)和镶嵌结构炭(mosaic carbon)发育,二者均由纹层织构组成。(2) 纹层光性特征为一轴晶负光性(No>Ne),光率体长轴No平行纹层面,短轴Ne垂直纹层面,其Kilby交叉图具“假二轴晶”光性特征。(3) 假二轴晶光性特征是纹层褶曲的结果,褶曲尽管不影响纹层反射光率体形态,但改变了其展布方向。
    结论 (1) 具强各向异性镜质体反射抑制的直接原因是纹层褶曲所致;(2) Kilby交叉图是判定镜质体是否存在强各向异性导致反射率抑制的有效方法;(3) 用双反射率(ΔRo)最大时的Rmax值代替其平均值,可校正反射率抑制,以准确反演岩浆接触变质煤的变质程度。

     

    Abstract:
    Objective For vitrinite with weak anisotropy, which proves uniaxial and optically negative, replacing random vitrinite reflectance (Rran) with the maximum vitrinite reflectance (Rmax) allows for the accurate correction of vitrinite reflectance suppression induced by anisotropy. However, as its anisotropy intensifies, vitrinite exhibits increasingly complex optical properties, rendering it challenging to reflect the thermal metamorphic temperature of vitrinite using Rmax.
    Methods This study investigated the strongly anisotropic vitrinite in coals and natural coke subjected to magma intrusion in the Shitai coal mine, Huaibei City, Anhui Province. Using a reflected-polarized light microscope (R-PLM), an ultra-high-definition scanning electron microscope (SEM), and tests on Rmax and the minimum vitrinite reflectance (Rmin), this study analyzed the microscopic textures, deep microfabrics, and optical properties of the vitrinite. Accordingly, the microscopic optical mechanisms underlying vitrinite reflectance suppression were explored.
    Results The strongly anisotropic vitrinite, formed by the contact metamorphism of magmas, contains flow-texture carbon and mosaic carbon, both composed of lamellar microfabrics. The lamellae in the carbon were uniaxial and optically negative (No > Ne), with the long axis No of the indicatrix parallel to the lamella surface and its short axis Ne perpendicular to the surface. The vitrinite exhibited the optical properties of pseudo-biaxial crystals in Kilby’s cross plot. The pseudo-biaxial crystals were formed by lamella folding. The underlying reason is that lamella folding changed the orientation of the lamellae’s reflected optical indicatrix (ROI) despite minimally influencing its morphology.
    Conclusions Lamella folding represents the direct cause of reflectance suppression in strongly anisotropic vitrinite. The Kilby’s cross plot serves as an effective method used to determine whether strong anisotropy induces vitrinite reflectance suppression. Replacing the average reflectance with Rmax corresponding to the maximum bireflectance (ΔRo) can correct reflectance suppression. This will help accurately determine the metamorphic grade of coals formed by magma intrusion-induced contact metamorphism through inversion.

     

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