The characteristics of pore structure and gas adsorption for water-immersion coal after drying
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摘要: 在富含水煤系或水力措施后的煤层中,受水溶液的浸泡,煤的孔隙结构及吸附特性发生改变,为了深入研究其变化规律,在实验室利用蒸馏水对2种不同变质程度煤样进行了长时间(60 d)浸泡,采用低温N2吸附实验和CO2吸附实验测试水浸前后煤样的孔隙结构变化规律,采用高压容量法测试水浸前后煤样的瓦斯吸附特性。结果表明,水浸干燥后煤体孔容和比表面积总体呈降低趋势。其中,低温N2吸附实验结果表明,煤体中大中孔的比表面积最高可降低48.9%;CO2吸附实验结果表明,水浸干燥后2种煤样的微孔孔容和比表面积也呈不同程度的降低趋势。将水浸煤样孔隙结构变化分为3个阶段,即矿物质溶出“增孔”阶段、煤基质局部膨胀变形“缩孔”阶段和煤基质整体溶胀变形“扩孔”阶段。此外,水浸干燥后煤对瓦斯的吸附能力下降,主要是由于水浸促使煤体产生膨胀变形,且导致微孔隙相互连通,从而降低了煤体微孔孔容和比表面积,降低瓦斯吸附能力。研究成果对进一步掌握富含水煤系或水力化措施后煤层的瓦斯抽采具有指导意义。Abstract: In order to investigate the characteristics of pore structure and methane adsorption for water-immersion coal after drying, two coal samples with different ranks were soaked in distilled water for a long time(60 d). Then, the low-temperature N2 adsorption experiments and CO2 adsorption experiments were carried out to investigate the changing rules of pore structure for coal before and after water immersion, and the high-pressure capacity method was used to test the characteristics of methane adsorption. Results showed that the pore volume and specific surface area of coal decreased after water immersion. According to the results of low-temperature N2 adsorption, the specific surface area of mesopore and macropore can be reduced by up to 48.9%. CO2 adsorption experiments shows that the pore volume and specific area of micropore decrease in varying degrees. The changes of pore structure consists of three stages, namely, the "pore increase" stage of mineral dissolution, the "shrinkage" of local expansion of coal matrix, and the "pore expansion" of overall swelling of coal matrix. In addition, the adsorption capacity of coal decreases after water immersion due to the interconnection of micropores caused by coal expansion and deformation, which reduces the pore volume and specific surface area of coal micropores. The research results have a guiding significance for gas drainage in water-rich coal measures and coal seam after hydraulic measures.
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Key words:
- water immersion /
- specific surface area /
- pore volume /
- pore structure /
- adsorption isotherm
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[1] 毛志勇,黄春娟,路世昌,等. 基于APSO-WLS-SVM的含瓦斯煤渗透率预测模型[J]. 煤田地质与勘探,2019,47(2):66-71.MAO Zhiyong,HUANG Chunjuan,LU Shichang,et al. Model of gas-bearing coal permeability prediction based on APSO-WLS-SVM[J]. Coal Geology & Exploration,2019,47(2):66-71. [2] 蓝航,陈东科,毛德兵. 我国煤矿深部开采现状及灾害防治分析[J]. 煤炭科学技术,2016,44(1):39-46.LAN Hang,CHEN Dongke,MAO Debing. Current status of deep mining and disaster prevention in China[J]. Coal Science and Technology,2016,44(1):39-46. [3] SI Leilei,ZHANG Hongtu,WEI Jianping,et al. Modeling and experiment for effective diffusion coefficient of gas in water-saturated coal[J]. Fuel,2021,284:118887. [4] SI Leilei,LI Zenghua,YANG Yongliang,et al. Modeling of gas migration in water-intrusion coal seam and its inducing factors[J]. Fuel,2017,210:398-409. [5] 顾范君. 桃园煤矿长时水淹后煤体瓦斯吸附及渗流特性的实验研究[D]. 徐州:中国矿业大学,2016. GU Fanjun. Experimental study of methane adsorption & seepage characteristics of coal in Taoyuan colliery after long-term water immersion[D]. Xuzhou:China University of Mining and Technology,2016. [6] 司磊磊. 水侵煤体瓦斯运移机理及应用研究[D]. 徐州:中国矿业大学,2019. SI Leilei. Mechanism of gas transport in water-intrusion coal seam and its application[D]. Xuzhou:China University of Mining and Technology,2019. [7] SI Leilei,LI Zenghua,XUE Dingzhi,et al. Modeling and application of gas pressure measurement in water-saturated coal seam based on methane solubility[J]. Transport in Porous Media,2017,119(1):163-179. [8] 王绪性,王杏尊,郭布民,等. 鄂尔多斯盆地东部深部煤层气井压裂工艺及实践[J]. 煤田地质与勘探,2019,47(1):92-95.WANG Xuxing,WANG Xingzun,GUO Bumin,et al. Technology and practice for deep CBM fracturing in eastern Ordos Basin[J]. Coal Geology & Exploration,2019,47(1):92-95. [9] DAVIES R J,MATHIAS S A,MOSS J,et al. Hydraulic fractures:How far can they go?[J]. Marine and Petroleum Geology,2012,37(1):1-6. [10] LIN Baiquan,YAN Fazhi,ZHU Chuanjie,et al. Cross-borehole hydraulic slotting technique for preventing and controlling coal and gas outbursts during coal roadway excavation[J]. Journal of Natural Gas Science and Engineering,2015,26:518-525. [11] 李锋,安世岗,邢真强. 水浸煤孔隙结构及自燃特性试验研究[J]. 煤炭科学技术,2019,49(增刊2):208-212.LI Feng,AN Shigang,XING Zhenqiang. Experimental study on pore structure and spontaneous combustion characteristics of submerged coal[J]. Coal Science and Technology,2019,49(Sup.2):208-212. [12] 秦小文. 浸水风干煤体低温氧化特性研究[D]. 徐州:中国矿业大学,2015. QIN Xiaowen. Study on characteristics of low temperature oxidation of air-dried coal soaked in water[D]. Xuzhou:China University of Mining and Technology,2015. [13] 李鑫. 浸水风干煤体自然氧化特性参数实验研究[D]. 徐州:中国矿业大学,2014. LI Xin. Experimental study on characteristic parameters of spontaneous combustion of soaked and air-dried coal[D]. Xuzhou:China University of Mining and Technology,2014. [14] 何勇军. 水浸烟煤低温氧化过程中微观结构变化规律研究[D]. 西安:西安科技大学,2016.HE Yongjun. Study on microstructure variation of soaked bitumite on low temperature oxidation process[D]. Xi'an:Xi'an University of Science and Technology,2016. [15] YANG Yongliang,SI Leilei,LI Zenghua,et al. Experimental study on effect of CO2-alkaline water two-phase gas displacement and coal wetting[J]. Energy & Fuels,2017,31(12):14374-14384. [16] YANG Yongliang,LI Zenghua,SI Leilei,et al. Study governing the impact of long-term water immersion on coal spontaneous ignition[J]. Arabian Journal for Science and Engineering,2016,42(4):1359-1369. [17] THOMMES M,KANEKO K,NEIMARK A V,et al. Physisorption of gases,with special reference to the evaluation of surface area and pore size distribution(IUPAC Technical Report)[J]. Pure and Applied Chemistry,2015,87(9/10):1051-1069. [18] JIN Kan,CHENG Yuanping,LIU Qingquan,et al. Experimental investigation of pore structure damage in pulverized coal:Implications for methane adsorption and diffusion characteristics[J]. Energy & Fuels,2016,30(12):10383-10395. [19] SI Leilei,LI Zenghua,YANG Yongliang,et al. Experimental investigation for pore structure and CH4 release characteristics of coal during pulverization process[J]. Energy & Fuels,2017,31(12):14357-14366. [20] 杨赫,程卫民,刘震,等. 注水煤体有效渗流通道结构分形特征核磁共振试验研究[J]. 岩土力学,2020,41(4):1279-1286.YANG He,CHENG Weimin,LIU Zhen,et al. Fractal characteristics of effective seepage channel structure of water infusion coal based on NMR experiment[J]. Rock and Soil Mechanics,2020,41(4):1279-1286. [21] LIU Peng,WANG Xiaofeng,LI Xiaofu,et al. Competitive adsorption characteristics of CH4/C2H6 gas mixtures on model substances,coal and shale[J]. Fuel,2020,279:118038. [22] 杨宏民,任子阳,王兆丰. 煤对气体吸附特征的研究现状及应用前景展望[J]. 煤,2009,18(8):1-4.YANG Hongmin,REN Ziyang,WANG Zhaofeng. Research and application prospects of gases adsorption characteristics of coal[J]. Coal,2009,18(8):1-4. [23] 桑树勋,朱炎铭,张井,等. 煤吸附气体的固气作用机理(Ⅱ):煤吸附气体的物理过程与理论模型[J]. 天然气工业,2005,25(1):16-18.SANG Shuxun,ZHU Yanming,ZHANG Jing,et al. Solid gas interaction mechanism of coal adsorbed gas(Ⅱ):Physical process and theoretical model of coal adsorbed gas[J]. Natural Gas Industry,2005,25(1):16-18. [24] YANG Yongliang,ZHANG Qiang,GU Fanjun,et al. Impacts of long-term water inrush on characteristics of coal gas adsorption and seepage[J]. International Journal of Oil,Gas and Coal Technology,2016,13(3):305-320. [25] WEN Guangcai,YANG Shuo,LIU Yanbao,et al. Influence of water soaking on swelling and microcharacteristics of coal[J]. Energy Science and Engineering,2019,8(1):1-11. [26] 孙旭明. 长期水浸煤中溶出物质及对煤自燃特性的影响研究[D]. 徐州:中国矿业大学,2015. SUN Xuming. Research on dissolved substances from coal and influence on propensity of coal to spontaneous combustion in the long-term soak[D]. Xuzhou:China University of Mining and Technology,2015. [27] 秦波涛,宋爽,戚绪尧,等. 浸水过程对长焰煤自燃特性的影响[J]. 煤炭学报,2018,43(5):1350-1357.QIN Botao,SONG Shuang,QI Xuyao,et al. Effect of soaking process on spontaneous combustion characteristics of long-flame coal[J]. Journal of China Coal Society,2018,43(5):1350-1357. [28] 潘俊锋,宁宇,蓝航,等. 基于千秋矿冲击性煤样浸水时间效应的煤层注水方法[J]. 煤炭学报,2012,37(增刊1):19-25.PAN Junfeng,NING Yu,LAN Hang,et al. Water injection methods in coal bed based on experiments of water immersion time effect of Qianqiu coal samples with burst trend[J]. Journal of China Coal Society,2012,37(Sup.1):19-25. [29] 季淮君,李增华,彭英健,等. 煤的溶剂萃取物成分及对煤吸附甲烷特性影响[J]. 煤炭学报,2015,40(4):856-862.JI Huaijun,LI Zenghua,PENG Yingjian,et al. Analysis of extracts and effects of them on methane adsorption characteristics of coal[J]. Journal of China Coal Society,2015,40(4):856-862.
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