稀有气体示踪地质流体及氦气富集研究进展

Research advances in noble gas tracing of geological fluid and helium enrichment

  • 摘要: 【背景】稀有气体因其化学惰性和在不同储库中同位素组成的差异性,成为示踪地质流体来源与演化过程的重要工具。氦气在作为稀有气体示踪剂的同时也是稀缺资源,其富集机制与勘探潜力备受关注。【方法】通过总结国内外典型气藏、火山喷气、地表热泉的地球化学数据,分析稀有气体来源解析中的干扰因素与端元值选择问题,总结稀有气体同位素在构建成藏模型、还原流体分配等多场景中的应用,并基于氦气生成潜力与运聚机理,凝练氦气成藏理论。【进展和展望】结合实例分析,提出3类氦气富集类型,分别为构造活动提升氦通量型(如青藏高原拉萨地块)、深埋高压页岩自封闭富集型(如四川盆地寒武、志留系页岩气藏)与水溶氦脱溶与烷烃气耦合富集成藏型(如塔里木盆地和田河气田)。拉萨地块理论壳源氦通量为全球平均氦通量的221~78 056倍,数值模拟结果为6 392~9 284倍,认为拉萨地块是理想的氦气聚集区;根据高压纳米孔隙系统显著抑制氦气扩散性,较早的生烃高峰期增加氦气“持续富集阶段”时间,认为埋藏较深的古老页岩气藏是理想的氦气聚集类型;晚期成藏的烷烃气在向圈闭运移时,能够提取广泛分布的古老地层水中氦气使其富集,认为这类气藏也是理想的氦气聚集类型。

     

    Abstract: Background Due to their chemical inertness and the differences in isotopic composition of their reservoirs, noble gases have become important tools for tracing the sources and evolution processes of geological fluids. As a noble gas tracer, helium is also a scarce resource, its enrichment mechanism and exploration potential have attracted much attention. Methods By summarizing the geochemical data of typical gas reservoirs, volcanic gases, and surface hot springs at home and abroad, Analysis of the interfering factors and terminal value screening in the source apportionment of rare gases, and summarizes the applications of noble gas isotopes in multiple disciplines such as constructing reservoir models and restoring fluid distribution. Based on the generation potential and migration and accumulation mechanisms of helium, the theoretical understanding of helium reservoir formation is refined. Advances and Prospects Combining case studies, three ideal helium enrichment types are proposed: Structural activities increase helium flux type (such as the Lhasa Block in the Qinghai-Tibet Plateau), deep-buried high-pressure shale with self-sealing enrichment (such as the Cambrian and Silurian shale gas reservoirs in the Sichuan Basin), and Water-soluble helium desolvation and alkane gas-coupled enrichment reservoir type (such as the Hetianhe Gas Field in the Tarim Basin). The Lhasa Block exhibits a theoretical crustal helium flux 221-78,056 times the global average, with numerical simulations constraining it to 6,392-9,284 times, suggesting that Lhasa Block is an ideal helium accumulation area. Considering the diffusivity of helium gas is significantly reduced in high-pressure nanopores, and the early peak of hydrocarbon generation prolongs the duration of the "Preservation and enrichment stage", this indicates that deep buried ancient shale gas reservoirs may be the ideal type for helium enrichment. During the migration of late-stage accumulated alkane gases into traps, they are capable of extracting helium from ancient formation water, leading to its enrichment, which is also an ideal helium accumulation type.

     

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