全流程煤基CCUS研究进展与前瞻

Research progress and prospects of the full flowsheet technology of coal-based CCUS

  • 摘要: 背景工程化全流程煤基CO2捕集、利用与封存(CCUS)技术是煤炭高效洁净利用和碳减排技术体系的关键,是实现我国能源安全和"双碳"战略目标的重大迫切需求。以笔者团队前期研究工作为基础,评述总结了全流程煤基CCUS技术当前发展现状,揭示煤基CCUS全流程技术的集成机制,探索建立了煤炭能源基地CCUS集群部署模式与方案,讨论前瞻了全流程煤基CCUS技术发展方向及其面临技术挑战。进展(1)低能耗高适配的煤基CO2捕集、安全高效的煤层CO2地质封存以及充分经济的煤矿区CO2利用是工程化全流程煤基CCUS技术的关键环节;全流程煤基CCUS技术集成是源汇匹配机制、技术参数匹配机制和系统优化机制耦合控制的结果,其中源汇匹配机制是通过CO2排放源与封存汇匹配的多维多约束路径优化实现煤基CCUS物理衔接,技术参数匹配机制是通过捕集-封存-利用端到端的关键运行参数协调设计,实现物理衔接设施的整体平稳运行和技术链条参数构建,系统优化机制是通过大数据平台、优化模型与智能算法等实现技术链条动态优化和系统最优化构建,机制间存在紧密互馈关系;(2)全流程煤基CCUS技术模式以"燃煤或煤化工工业源碳捕集、含煤盆地或煤层碳地质封存、煤矿区CO2利用"为鲜明特色,以煤炭能源基地CCUS集群为呈现形式,以新疆准噶尔盆地、鄂尔多斯盆地为代表的大型煤炭基地CCUS集群将为我国煤炭能源产业低碳化高质量发展提供关键技术支撑。展望以低成本碳捕集-深部煤层气/煤系气枯竭气藏CO2地质封存等含煤盆地安全高效CO2地质封存-煤矿区CO2高值化综合利用一体化技术体系为内涵的大型煤炭基地CCUS集群部署技术是其发展主流方向,煤化工尾气驱煤层气封存、富氧燃烧等燃煤烟气驱煤层气封存、新能源基地调峰煤电CO2高效捕集与规模化转化利用、煤电基地CO2捕集与关闭矿井采空区储碳储能为代表的技术有望成为全流程煤基CCUS技术的重要拓展方向。

     

    Abstract: The engineering-scale full flowsheet technology of coal-based CCUS is a pivotal component of the technology system for efficient, clean coal utilization and carbon emission reduction. It represents a critical and urgent requirement for achieving China’s energy security and the “Dual Carbon” strategic goals. Based on the authors’prior research, this paper reviews the current development status of the full flowsheet coal-based CCUS technology, reveals its integration mechanisms, explores and establishes deployment models and strategies for CCUS clusters in coal energy bases , and discusses future development directions and associated technical challenges. Progress: (1) Low-energy-consumption and highly adaptable coal-based CO2 capture, safe and efficient geological storage of CO2 in coal seams, and sufficient, economically feasible CO2 utilization in coal mining areas constitute the key links in the engineering-scale full flowsheet coal-based CCUS technology. The integration of this full flowsheet technology is driven by the coupled control of source-sink matching mechanisms, technical parameter matching mechanisms, and system optimization mechanisms. The source-sink matching mechanism realizes the physical linkage of coal-based CO2 capture, geological storage, and utilization facilities through multidimensional, constraint-based path optimization. The technical parameter matching mechanism ensures the stable operation of physically connected facilities and the construction of technical chain parameters through coordinated design of key end-to-end operational parameters across capture , storage , and utilization. The system optimization mechanism enables the dynamic optimization of the technical chain and the construction of optimal system configurations through big data platforms, optimization models, and intelligent algorithms. These mechanisms exhibit strong interdependencies and mutual feedback relationships. (2) The full flowsheet coal-based CCUS technology model is characterized by “CO2 capture from coal-fired or coal chemical industrial sources, geological storage in coal-bearing basins or coal seams, and CO2 utilization in coal mining areas,” and is implemented in the form of CCUS clusters in coal energy bases. Representative large-scale coal base CCUS clusters in the Junggar Basin and the Ordos Basin will provide critical technological support for the low-carbon, high-quality development of China’s coal industry. Outlook: The mainstream direction for the development of full flowsheet coal-based CCUS technology lies in the deployment of large-scale CCUS clusters in coal bases, centered on integrated systems comprising low-cost CO2 capture, safe and efficient geological storage in deep coalbed methane (CBM) or coal-measure gas-depleted reservoirs within coal-bearing basins, and high-value comprehensive utilization of CO2 in mining areas. Technologies such as ECBM storage driven by coal chemical tail gas, ECBM storage utilizing oxy-fuel combustion flue gas, efficient CO2 capture and large-scale conversion/utilization for peak-shaving coal power in new energy bases , and CO2 capture from coal-fired power bases coupled with carbon and energy storage in abandoned mine goafs are anticipated to become key expansion directions for the full flowsheet coal-based CCUS technology.

     

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