李久庆, 秦勇, 陈义林. 超无烟煤中石墨微晶产出状态与成因[J]. 煤田地质与勘探, 2020, 48(1): 27-33. DOI: 10.3969/j.issn.1001-1986.2020.01.004
引用本文: 李久庆, 秦勇, 陈义林. 超无烟煤中石墨微晶产出状态与成因[J]. 煤田地质与勘探, 2020, 48(1): 27-33. DOI: 10.3969/j.issn.1001-1986.2020.01.004
LI Jiuqing, QIN Yong, CHEN Yilin. Occurrence and origin of graphite microcrystal in meta-anthracite[J]. COAL GEOLOGY & EXPLORATION, 2020, 48(1): 27-33. DOI: 10.3969/j.issn.1001-1986.2020.01.004
Citation: LI Jiuqing, QIN Yong, CHEN Yilin. Occurrence and origin of graphite microcrystal in meta-anthracite[J]. COAL GEOLOGY & EXPLORATION, 2020, 48(1): 27-33. DOI: 10.3969/j.issn.1001-1986.2020.01.004

超无烟煤中石墨微晶产出状态与成因

Occurrence and origin of graphite microcrystal in meta-anthracite

  • 摘要: 超无烟煤(也称变质无烟煤)中广泛发育石墨微晶,为深入分析煤中石墨微晶产出特征及成因,以福建省永安煤田典型样品为例,采用光学显微镜、扫描电镜和透射电镜等测试方法,识别并分析煤中石墨微晶的光学性质、物质组成、晶体结构等特征,并探讨其成因。结果显示:石墨微晶主要产出于煤中微裂缝和空腔内,多数具有类似于石油焦的纤维状显微结构,可见气泡膜状结构;石墨微晶最大反射率为9.29%~10.83%,远远高于煤中原有显微组分;正交偏光加石膏试板观测条件下,石墨微晶呈现一级黄、二级蓝干涉色以及镶嵌状、区域状、纤维状等显微结构,局部定向性明显。扫描电镜加电子探针探测显示,石墨微晶多呈鳞片状并见流动状结构和气孔构造,同时显示出纯碳特点。高分辨率透射电镜观测到石墨微晶晶格条纹呈平直定向排列,选区电子衍射呈现典型的石墨晶格环斑模式。初步分析认为,煤中石墨微晶的碳质来源于高度熔融的(变)壳质组和富氢(变)镜质体,热源为侵入煤田周边及盆地底部的燕山期花岗岩,熔融含碳物质在孔缝空间内汇聚流动并在高温下脱除杂质元素,然后在强大岩浆侵位压力下结晶形成秩理性显著的石墨微晶;同时,也不排除渗出沥青质体再次活化形成研究区煤中石墨微晶的可能性。移动阅读

     

    Abstract: Microcrystalline graphite occurs widely in meta-anthracite, to analyse the occurrence characteristics and genesis of graphite microcrystal, by methods of optical microscope, scanning electron microscope and transmission electron microscope, the optical properties, material composition and crystal structure of graphite microcrystal in Yong'an coal field of Fujian Province were characterized, and their genesis was preliminarily discussed. The results show that the graphite microcrystal in coal occurs mainly in micro cracks and cavities, and most of them have fibrous microstructure similar to petroleum coke, with bubble membrane structure. The maximum reflectivity of the microcrystal ranges from 9.29% to 10.83% and significantly stronger than the original components in coal. Using the orthogonal polarized light plus gypsum test plate, the microcrystal shows the interference color of primary yellow and secondary blue as well as the mosaic, regional and fibrous microstructure, with obvious local orientation. Under scanning electron microscopy and electron probe microanalysis, the microcrystal was mostly scaly, with flowing and gas pore structures, and showed the characteristics of pure carbon. Under high-resolution TEM, the straight and directional lattice stripes of the microcrystal were observed, and the selected area electron diffraction shows a typical lattice ring and spot of graphite. It was preliminary considered that the carbon of the graphite microcrystal in coal came from the highly molten meta-exinite and hydrogen-rich meta-vitrinite, and the heat source was the Yanshanian granite intruding into the periphery of the coal field and the bottom of the basin. The molten carbonaceous materials flowed into the pore and fissure space, in which the impurity elements were removed at high temperature, and then formed the graphite microcrystal with significant directivity under the strong magma emplacement pressure. At the same time, it was also possible that the microcrystalline was formed by the transformation of exsudatinite in coal for the study area.

     

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