臧立彬, 崔虎锋, 李庆春. 弱氧化气氛下烟煤热解特性及热解产物组成[J]. 煤田地质与勘探, 2020, 48(5): 34-39. DOI: 10.3969/j.issn.1001-1986.2020.05.004
引用本文: 臧立彬, 崔虎锋, 李庆春. 弱氧化气氛下烟煤热解特性及热解产物组成[J]. 煤田地质与勘探, 2020, 48(5): 34-39. DOI: 10.3969/j.issn.1001-1986.2020.05.004
ZANG Libin, CUI Hufeng, LI Qingchun. Pyrolysis characteristics and pyrolysis product composition of bituminous coal under weak oxidizing atmosphere[J]. COAL GEOLOGY & EXPLORATION, 2020, 48(5): 34-39. DOI: 10.3969/j.issn.1001-1986.2020.05.004
Citation: ZANG Libin, CUI Hufeng, LI Qingchun. Pyrolysis characteristics and pyrolysis product composition of bituminous coal under weak oxidizing atmosphere[J]. COAL GEOLOGY & EXPLORATION, 2020, 48(5): 34-39. DOI: 10.3969/j.issn.1001-1986.2020.05.004

弱氧化气氛下烟煤热解特性及热解产物组成

Pyrolysis characteristics and pyrolysis product composition of bituminous coal under weak oxidizing atmosphere

  • 摘要: 为提高轻质焦油和煤气产率,选取陕西红柳林烟煤为研究对象,采用固定床反应器对比分析N2气氛和弱氧气氛下(N2+O2)煤的热解产物产率分布及组成特性。结果表明:随着O2的加入,半焦和焦油产率显著降低,CO和CO2气体产率显著增大,导致总气体产率增大;由于发生氧化燃烧反应,随着热解气氛中氧含量的增大,H2、CH4和C2—C3产率逐渐降低,在此过程中水产率变化幅度较小;弱氧气氛下焦油分解温度大于N2气氛,酚类物、脂肪烃及苯系物在弱氧气氛下热解焦油中的相对含量较低,且多环芳烃相对含量明显大于N2气氛下热解焦油。当热解温度为800℃,过量空气系数ER=0.14时,焦油产率为6.22%,H2产率14.01 mg/L,焦油和H2产率达到最佳值。由于弱氧气氛下热解得到半焦的石墨化程度低于N2气氛下的热解半焦,导致弱氧气氛下半焦反应活性大于N2气氛。研究结果为固定床热解烟煤制备高值燃料提供基础数据。

     

    Abstract: In order to improve the light tar and gas yield, the yield distribution and composition characteristics of pyrolysis products of bituminous coal from Shaanxi Hongliulin in the nitrogen atmosphere and weak oxygen atmosphere were studied in a fixed bed reactor. The results showed that the yield of char and tar were reduced under the weak oxygen atmosphere, and the yield of CO and CO2 increased significantly, leading to the increase of total gas yield. Due to the oxidation combustion reaction, the yield of H2, CH4 and C2-C3 gradually decreased with the increase of oxygen content in the pyrolysis atmosphere, and the water content changed little during the process. The decomposition temperature of pyrolysis tar in the micro oxygen atmosphere was more than that of N2 atmosphere. When the pyrolysis temperature was 800℃ and ER=0.14, the tar yield was 6.22%, the H2 yield was 14.01 mg/L, and the tar and H2 product yield reached the best value. The relative content of aliphatic hydrocarbons, phenols and benzene series in pyrolysis tar was lower, and the relative content of PAHs was higher than that of pyrolysis tar in N2. The graphitization degree of char in the weak oxygen atmosphere was lower than that of pyrolysis char in N2, and the gasification reactivity of char in micro oxygen atmosphere was greater than that in N2. The results provide basic data for the preparation of high-value fuel by pyrolysis of bituminous coal in fixed bed.

     

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