张明杰, 刘浩, 贾天让, 龚泽, 杨明鑫. 颗粒煤超临界态甲烷吸附相密度特征研究[J]. 煤田地质与勘探, 2021, 49(5): 105-113. DOI: 10.3969/j.issn.1001-1986.2021.05.012
引用本文: 张明杰, 刘浩, 贾天让, 龚泽, 杨明鑫. 颗粒煤超临界态甲烷吸附相密度特征研究[J]. 煤田地质与勘探, 2021, 49(5): 105-113. DOI: 10.3969/j.issn.1001-1986.2021.05.012
ZHANG Mingjie, LIU Hao, JIA Tianrang, GONG Ze, YANG Mingxin. Adsorption phase density characteristics of supercritical methane of granular coal[J]. COAL GEOLOGY & EXPLORATION, 2021, 49(5): 105-113. DOI: 10.3969/j.issn.1001-1986.2021.05.012
Citation: ZHANG Mingjie, LIU Hao, JIA Tianrang, GONG Ze, YANG Mingxin. Adsorption phase density characteristics of supercritical methane of granular coal[J]. COAL GEOLOGY & EXPLORATION, 2021, 49(5): 105-113. DOI: 10.3969/j.issn.1001-1986.2021.05.012

颗粒煤超临界态甲烷吸附相密度特征研究

Adsorption phase density characteristics of supercritical methane of granular coal

  • 摘要: 查明颗粒煤超临界态甲烷吸附相密度特征是研究温度、压力影响煤样吸附甲烷量的基础。选用安阳–鹤壁煤田鹤壁六矿与龙山矿颗粒煤样,借助磁悬浮天平等温吸附仪测量温度为308、313和318 K,压力为1~24 MPa下的等温吸附线。利用截距法、Langmuir三元模型拟合法与液相密度法分别计算超临界甲烷吸附饱和时的吸附相密度,分析其影响因素,并通过定吸附相体积的方法,一方面计算未吸附饱和时的吸附相密度,对峰值型拐点与过剩吸附量出现负值的实验现象进行解释,另一方面校正出较为理想的绝对吸附量。吸附相密度的计算结果表明,甲烷吸附相密度受温度、压力和煤变质程度的影响:随温度升高而降低,随压力升高先快速增加,后逐渐变缓,测量范围内吸附饱和时,无烟煤吸附相密度为121.60~136.17 kg/m3,贫瘦煤为73.29~76.96 kg/m3;绝对吸附量的计算结果表明,采用液相密度法校正出的绝对吸附量会出现负值,明显与实际不符,用截距法和Langmuir三元模型法校正的绝对吸附量会因实验条件的变化而改变,结合吸附常数b值的变化规律,发现用Langmuir三元模型法描述超临界甲烷的吸附行为最为恰当。

     

    Abstract: Finding out the characteristics of supercritical methane adsorption phase density of granular coal is the basis of studying the influence of temperature and pressure on methane adsorption amount of coal sample. Granular coal samples collected from Hebi No.6 Mine and Longshan Mine in Anyang-Hebi Coalfield were used to measure the isothermal adsorption lines at temperatures of 308 K, 313 K and 318 K, and pressures of 1-24 MPa by magnetic suspension balance isotherm adsorption device. The intercept method, Langmuir ternary model fitting method and liquid phase density method were used to calculate the adsorbed phase density at adsorption saturation and find out the influencing factors. By the method of constant adsorption phase volume, on the one hand, the adsorbed phase density were calculated, and the experimental phenomenon of negative value and peak inflection point of excess adsorption capacity was explained; on the other hand, a relatively ideal absolute adsorption capacity has been calibrated. The calculation results of adsorbed phase density show that the methane adsorption phase density is affected by temperature, pressure and coal metamorphism degree: it decreases with the increase of temperature, and increases rapidly with the increase of pressure at first, and then gradually slows down. The saturated adsorption phase density of anthracite is between 121.60-137.02 kg/m3, and that of meager lean coal is between 73.29-76.96 kg/m3. The calculation results of absolute adsorption capacity show that the absolute adsorption capacity corrected by liquid density method would appear negative value, which is obviously inconsistent with the reality; the absolute adsorption capacity corrected by intercept method and Langmuir ternay model method changes with the change of experimental conditions, in combination with the variation of adsorption constant b, the Langmuir ternary model is found to be the most suitable method to describe the adsorption behavior of supercritical methane.

     

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